Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Metalloporphyrins in bio-inspired photocatalytic conversions
Δημιουργός/Συγγραφέας:	Charisiadis, Asterios Nikolaou, Vasilis Nikoloudakis, Emmanouil Ladomenou, Kalliopi [EL] Χαραλαμπίδης, Γεώργιος[EN] Charalambidis, Georgios Coutsolelos, Athanassios G
Ημερομηνία:	2025-03-19
Γλώσσα:	Αγγλικά
DOI:	10.1039/d4cc06655c
Άλλο:	40009006
Περίληψη:	Numerous natural systems contain porphyrin derivatives that facilitate important catalytic processes; thus, developing biomimetic photocatalytic systems based on synthetic metalloporphyrins constitutes a rapidly advancing and fascinating research field. Additionally, porphyrins are widely investigated in a plethora of applications due to their highly versatile structure, presenting advantageous photoredox, photophysical and photochemical properties. Consequently, such metallated tetrapyrrolic macrocycles play a prominent role as photosensitizers and catalysts in developing artificial photosynthetic systems that can store and distribute energy through fuel forming reactions. This review highlights the advances in the field of metalloporphyrin-based biomimetic photocatalysis, particularly targeting water splitting, including both hydrogen and oxygen evolution reactions, carbon dioxide reduction and alcohol oxidation. For each photocatalytic system different approaches are discussed, concerning either structural modifications of the porphyrin derivatives or the phase in which the process takes place, i.e. homogenous or heterogenous. The most important findings for each porphyrin-based photocatalytic reaction are presented and accompanied by the analysis of mechanistic aspects when possible. Finally, the perspectives and limitations are discussed, providing future guidelines for the development of highly efficient metalloporphyrin-based biomimetic systems towards energy and environmental applications.
Τίτλος πηγής δημοσίευσης:	Chemical communications (Cambridge, England)
Τόμος/Κεφάλαιο:	61
Τεύχος:	24
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry [EL] Βιοτεχνολογία[EN] Biotechnology
Λέξεις-Κλειδιά:	metalloporphyrins biomimetic photocatalysis photosensitizers solar fuels
Χρηματοδότης:	Bodossaki Foundation
Χρηματοδοτικό πρόγραμμα:	HORIZON TMA MSCA Postdoctoral Fellowships – European Fellowships (HORIZON-TMA-MSCA-PF-EF)
Αναγνωριστικό χρηματοδοτικού προγράμματος:	101064765 (SOLAR-CAT)
Κάτοχος πνευματικών δικαιωμάτων:	© 2025 The Author(s). Published by the Royal Society of Chemistry
Όροι και προϋποθέσεις δικαιωμάτων:	This article is licensed under a Creative Commons Attribution 4.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.
Ηλεκτρονική διεύθυνση στον εκδότη (link):	https://doi.org/10.1039/d4cc06655c
Σημειώσεις:	Dr Emmanouil Nikoloudakis gratefully acknowledges the Bodossaki Foundation for financial support. Dr. Vasilis Nikolaou acknowledges the support of the HORIZON TMA MSCA Postdoctoral Fellowships – European Fellowships (HORIZON-TMA-MSCA-PF-EF) action program under the MSCA Postdoctoral Fellowships 2021 call (HORIZON-MSCA-2021-PF-01), through grant agreement no. 101064765 (SOLAR-CAT).
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο