Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Ionic diffusion in post-lithium batteries
Δημιουργός/Συγγραφέας:	Balaouras, Vasileios [EL] Κελαϊδής, Νικόλαος[EN] Kelaidis, Nikolaos Daskalopulu, Aspassia Kuganathan, Navaratnarajah Chroneos, Alexander
Ημερομηνία:	2025
Γλώσσα:	Αγγλικά
ISSN:	1432-8488 1433-0768
DOI:	10.1007/s10008-025-06278-1
Περίληψη:	Although lithium-ion batteries are the mainstream choice for batteries, they raise sustainability, safety, and economic concerns that need to be addressed. Lithium resources might be inadequate for the ever-increasing demand, so alternative, relatively abundant and sustainable materials for battery applications are sought. Alternative ionic species, such as sodium-ion, magnesium-ion, and calcium-ion oxides are being explored as next-generation electrode and electrolyte materials beyond lithium-ion technology. Sodium, magnesium, and calcium are far more abundant than lithium, they are cheaper and more sustainable. However, the replacement of lithium with these larger cations does not come without challenges. A major limitation that must be overcome is that they exhibit reduced diffusion kinetics in comparison to lithium. This is of critical importance for the cathode and electrolyte and, hence, the overall performance of the battery. To facilitate faster diffusion coefficients for these larger cations, it is important to accommodate them in appropriate crystal lattices. Furthermore, kinetics can be accelerated using defect engineering strategies. Atomistic simulation is an efficient way to accelerate progress in the quest for efficient post-lithium battery materials. In this review, we discuss recent advances, including the deployment of artificial intelligence (AI) techniques, in the investigation of sodium-ion, magnesium-ion, and calcium-ion oxides for energy storage applications.
Τίτλος πηγής δημοσίευσης:	Journal of Solid State Electrochemistry
Τόμος/Κεφάλαιο:	29
Τεύχος:	9
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry [EL] Νανοτεχνολογία[EN] Nanotechnology
Λέξεις-Κλειδιά:	batteries diffusion defect engineering doping sodium magnesium calcium
Κάτοχος πνευματικών δικαιωμάτων:	© The Author(s) 2025
Όροι και προϋποθέσεις δικαιωμάτων:	Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Ηλεκτρονική διεύθυνση στον εκδότη (link):	https://doi.org/10.1007/s10008-025-06278-1
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο