Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Towards Construction of the “Periodic Table” of 1-Methylbenzotriazole
Δημιουργός/Συγγραφέας:	Stamou, Christina Lada, Zoi G. Paschalidou, Sophia [EL] Χασάπης, Χρήστος[EN] Chasapis, Christos Perlepes, Spyros P.
Ημερομηνία:	2024
Γλώσσα:	Αγγλικά
ISSN:	2304-6740
DOI:	10.3390/inorganics12080208
Περίληψη:	Metal complexes of benzotriazole-type ligands continue to attract the intense interest of many inorganic chemistry groups around the world for a variety of reasons, including their aesthetically beautiful structures, physical properties and applications. 1-methylbenzotriazole (Mebta) is the N-substituted archetype of the parent 1H-benzotriazole. The first attempt to build a “periodic table” of Mebta, which includes its complexes with several metal ions, is described in this work. This, at first glance, trivial ligand has led to interesting results in terms of the chemistry, structures and properties of its metal complexes. This work reviews the to-date published coordination chemistry of Mebta with Mn(II), Fe(II), Fe(III), Co(II), Ni(II), Cu(I), Cu(II), Zn(II), Pd(II), Au(I) and {UVIO2}2+, with emphasis on their preparations, reactivity, structures and properties. Unpublished results from our group comprising other Co(II), Ni(II), Cu(II) and Zn(II) complexes, as well as Cd(II), Hg(II), Ag(I), In(III) and Sn(IV) ones are briefly reported. Mebta can also provide access to 1D and 3D heterometallic thiocyanato-bridged Co(II)/Hg(II) and Ni(II)/Hg(II) compounds. In almost all cases, Mebta behaves as a monodentate ligand with the nitrogen of position 3 of the azole ring as the donor atom. However, there are two copper complexes in which this molecule adopts a bidentate bridging coordination behavior. Our efforts to complete the “periodic table” of Mebta are continued.
Τίτλος πηγής δημοσίευσης:	Inorganics
Τόμος/Κεφάλαιο:	12
Τεύχος:	8
Θεματική Κατηγορία:	[EL] Ανόργανη χημεία[EN] Inorganic chemistry [EL] Κρυσταλλογραφία[EN] Crystallography [EL] Τοξικολογία[EN] Toxicology. Poisons
Λέξεις-Κλειδιά:	benzotriazole-type ligands coordination chemistry 1-methylbenzotriazole metal complexes reactivity structures synthesis
Κάτοχος πνευματικών δικαιωμάτων:	© 2024 by the authors. Licensee MDPI, Basel, Switzerland.
Όροι και προϋποθέσεις δικαιωμάτων:	This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).
Ηλεκτρονική διεύθυνση στον εκδότη (link):	https://doi.org/10.3390/inorganics12080208
Εμφανίζεται στις συλλογές:	Ινστιτούτο Χημικής Βιολογίας - Επιστημονικό έργο